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Thermodynamic assessment of hydrogen production via solar thermochemical cycle based on MoO

Jiahui JIN, Lei WANG, Mingkai FU, Xin LI, Yuanwei LU

《能源前沿（英文）》 2020年 第14卷 第1期   页码 71-80 doi: 10.1007/s11708-019-0652-9

摘要： Inspired by the promising hydrogen production in the solar thermochemical (STC) cycle based on non-stoichiometric oxides and the operation temperature decreasing effect of methane reduction, a high-fuel-selectivity and CH -introduced solar thermochemical cycle based on MoO /Mo is studied. By performing HSC simulations, the energy upgradation and energy conversion potential under isothermal and non-isothermal operating conditions are compared. In the reduction step, MoO : CH = 2 and 1020 K< <1600 K are found to be most favorable for syngas selectivity and methane conversion. Compared to the STC cycle without CH , the introduction of methane yields a much higher hydrogen production, especially at the lower temperature range and atmospheric pressure. In the oxidation step, a moderately excessive water is beneficial for energy conversion whether in isothermal or non-isothermal operations, especially at H O: Mo= 4. In the whole STC cycle, the maximum non-isothermal and isothermal efficiency can reach 0.417 and 0.391 respectively. In addition, the predicted efficiency of the second cycle is also as high as 0.454 at = 1200 K and = 400 K, indicating that MoO could be a new and potential candidate for obtaining solar fuel by methane reduction.

关键词： MoO2/Mo based on solar thermochemical cycle     methanothermal reduction     isothermal and non-isothermal operation     syngas and hydrogen production     thermodynamic analysis    

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Analysis of radiation heat transfer and temperature distributions of solar thermochemical reactor for

Bachirou GUENE LOUGOU, Yong SHUAI, Xiang CHEN, Yuan YUAN, Heping TAN, Huang XING

《能源前沿（英文）》 2017年 第11卷 第4期   页码 480-492 doi: 10.1007/s11708-017-0506-2

摘要： This paper investigated radiation heat transfer and temperature distributions of solar thermochemical reactor for syngas production using the finite volume discrete ordinate method (fvDOM) and P1 approximation for radiation heat transfer. Different parameters including absorptivity, emissivity, reflection based radiation scattering, and carrier gas flow inlet velocity that would greatly affect the reactor thermal performance were sufficiently investigated. The fvDOM approximation was used to obtain the radiation intensity distribution along the reactor. The drop in the temperature resulted from the radiation scattering was further investigated using the P1 approximation. The results indicated that the reactor temperature difference between the P1 approximation and the fvDOM radiation model was very close under different operating conditions. However, a big temperature difference which increased with an increase in the radiation emissivity due to the thermal non-equilibrium was observed in the radiation inlet region. It was found that the incident radiation flux distribution had a strong impact on the temperature distribution throughout the reactor. This paper revealed that the temperature drop caused by the boundary radiation heat loss should not be neglected for the thermal performance analysis of solar thermochemical reactor.

关键词： solar thermochemical reactor     incident radiation flux     temperature distribution     radiation absorptivity     radiation emissivity     thermal performance analysis    

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Revealing the GHG reduction potential of emerging biomass-based CO utilization with an iron cycle system

《环境科学与工程前沿（英文）》 2023年 第17卷 第10期 doi: 10.1007/s11783-023-1727-8

摘要：

● Greenhouse gas mitigation by biomass-based CO2 utilization with a Fe cycle system.

关键词： Carbon dioxide utilization     Hydrothermal reactions     Biomass-based CO2 reduction     Simulation     Ex-ante LCA    

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Piezocatalytic performance of FeO−BiMoO catalyst for dye degradation

《化学科学与工程前沿（英文）》 2023年 第17卷 第6期   页码 716-725 doi: 10.1007/s11705-022-2265-9

摘要： A Fe2O3−Bi2MoO6 heterojunction was synthesized via a hydrothermal method. Scanning electron microscopy, transmission electron microscopy, energy-dispersive X-ray, powder X-ray diffraction, Fourier transform infrared spectroscopy and ultra-violet−visible near-infrared spectrometry were performed to measure the structures, morphologies and optical properties of the as-prepared samples. The various factors that affected the piezocatalytic property of composite catalyst were studied. The highest rhodamine B degradation rate of 96.6% was attained on the 3% Fe2O3−Bi2MoO6 composite catalyst under 60 min of ultrasonic vibration. The good piezocatalytic activity was ascribed to the formation of a hierarchical flower-shaped microsphere structure and the heterostructure between Fe2O3 and Bi2MoO6, which effectively separated the ultrasound-induced electron–hole pairs and suppressed their recombination. Furthermore, a potential piezoelectric catalytic dye degradation mechanism of the Fe2O3−Bi2MoO6 catalyst was proposed based on the band potential and quenching effect of radical scavengers. The results demonstrated the potential of using Fe2O3−Bi2MoO6 nanocomposites in piezocatalytic applications.

关键词： piezocatalysis     Fe2O3−Bi2MoO6     dye decomposition     ultrasonic vibration    

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中国高温气冷堆制氢发展战略研究

张平,徐景明,石磊,张作义

《中国工程科学》 2019年 第21卷 第1期   页码 20-28 doi: 10.15302/J-SSCAE-2019.01.004

摘要：

核能制氢是一种有应用前景的高效、大规模、无排放的制氢技术，有望在氢气大规模集中供应的场景中起到重要作用。高温气冷堆是最适于核能制氢的堆型，在我国已有几十年的研发基础，目前正在国家科技重大专项支持下建造高温气冷堆示范电站。本文介绍了核能制氢技术的特点和主流的核能制氢工艺包括热化学碘硫循环、混合硫循环和高温蒸汽电解的原理，对国际上核能制氢技术发展现状进行了简要综述，并概述了清华大学在该领域的研发现状。此外对核能制氢的安全性、技术经济评价等问题进行了讨论，在此基础上对与高温气冷堆耦合的制氢技术进行了评价，并以氢气直接还原炼铁为例探讨了高温气冷堆制氢在工业领域的应用前景。最后对我国高温气冷堆制氢技术的发展路线进行了探讨。

关键词： 高温气冷堆     能制氢     热化学循环     高温电解     技术路线    

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下一代太阳能光热电站中熔融氯盐技术研发进展 Review

丁文进, Thomas Bauer

《工程（英文）》 2021年 第7卷 第3期   页码 334-347 doi: 10.1016/j.eng.2020.06.027

摘要：

结合热能储存（TES，以下简称储热）的太阳能光热发电（concentrated solar power, CSP）技术是未来可再生能源系统中最具应用前景的发电技术之一本文首先介绍了下一代CSP技术及其储热技术的研发进展，之后重点介绍了基于熔融氯盐（如MgCl2/NaCl/KCl混合盐）的先进储热技术。MgCl2/NaCl/KCl具有与商业熔融硝酸盐相似的热物性、更高的热稳定性（> 800 ℃）和更低的材料成本（< 0.35 USD∙kg–1

关键词： 太阳能     太阳能光热发电（CSP）     热能储存（TES）     导热流体（HTF）     超临界二氧化碳动力循环     腐蚀控制    

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Review of the direct thermochemical conversion of lignocellulosic biomass for liquid fuels

Jianchun JIANG,Junming XU,Zhanqian SONG

《农业科学与工程前沿（英文）》 2015年 第2卷 第1期   页码 13-27 doi: 10.15302/J-FASE-2015050

摘要： Increased demand for liquid transportation fuels, environmental concerns and depletion of petroleum resources requires the development of efficient conversion technologies for production of second-generation biofuels from non-food resources. Thermochemical approaches hold great potential for conversion of lignocellulosic biomass into liquid fuels. Direct thermochemical processes convert biomass into liquid fuels in one step using heat and catalysts and have many advantages over indirect and biological processes, such as greater feedstock flexibility, integrated conversion of whole biomass, and lower operation costs. Several direct thermochemical processes are employed in the production of liquid biofuels depending on the nature of the feedstock properties: such as fast pyrolysis/liquefaction of lignocellulosic biomass for bio-oil, including upgrading methods, such as catalytic cracking and hydrogenation. Owing to the substantial amount of liquid fuels consumed by vehicular transport, converting biomass into drop-in liquid fuels may reduce the dependence of the fuel market on petroleum-based fuel products. In this review, we also summarize recent progress in technologies for large-scale equipment for direct thermochemical conversion. We focus on the technical aspects critical to commercialization of the technologies for production of liquid fuels from biomass, including feedstock type, cracking catalysts, catalytic cracking mechanisms, catalytic reactors, and biofuel properties. We also discuss future prospects for direct thermochemical conversion in biorefineries for the production of high grade biofuels.

关键词： lignocellulosic biomass     thermochemical     liquid fuels     upgrading     biofuels    

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SiO2 passivation layer grown by liquid phase deposition for silicon solar cell application

Yanlin CHEN,Sihua ZHONG,Miao TAN,Wenzhong SHEN

《能源前沿（英文）》 2017年 第11卷 第1期   页码 52-59 doi: 10.1007/s11708-016-0429-3

摘要： Surface passivation is one of the primary requirements for high efficient silicon solar cells. Though the current existed passivation techniques are effective, expensive equipments are required. In this paper, a comprehensive understanding of the SiO passivation layer grown by liquid phase deposition (LPD) was presented, which was cost-effective and very simple. It was found that the post-annealing process could significantly enhance the passivation effect of the LPD SiO film. Besides, it was revealed that both chemical passivation and field-effect passivation mechanisms played important roles in outstanding passivation effect of the LPD SiO film through analyzing the minority carrier lifetime and the surface recombination velocity of n-type and p-type silicon wafers. Although the deposition parameters had little influence on the passivation effect, they affected the deposition rate. Therefore, appropriate deposition parameters should be carefully chosen based on the compromise of the deposition rate and fabrication cost. By utilizing the LPD SiO film as surface passivation layer, a 19.5%-efficient silicon solar cell on a large-scale wafer (156 mm × 156 mm) was fabricated.

关键词： Si solar cell     passivation     SiO2     liquid phase deposition     carrier lifetime    

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Life cycle assessment and economic analysis of HFC-134a production from natural gas compared with oil-basedand coal-based production

《化学科学与工程前沿（英文）》 2022年 第16卷 第12期   页码 1713-1725 doi: 10.1007/s11705-022-2210-y

摘要： China is the largest producer and consumer of HFC-134a (1,1,1,2-tetrafluoroethane) in the world. Coal-based route is mainly adopted to produce HFC-134a, which suffers from large waste and CO2 emissions. Natural gas is a low-carbon and clean energy resource, and no research has been found on the environment and economy of producing HFC-134a from natural gas. In this study, CML 2001 method was used to carry out the life cycle assessment of natural gas (partial oxidation)-based and natural gas (plasma cracking)-based routes (abbreviated as gas(O)-based and gas(P)-based routes, respectively), and their environmental performances were compared with coal-based and oil-based routes. Meanwhile, considering that China is vigorously promoting the transformation of energy structure, and the application of electric heating equipment to replace fossil-based heating equipment in industrial field, which has a great impact on the environmental performance of the production processes, the authors conducted a scenario analysis. The results showed that the gas(O)-based route had the most favourable environmental benefits. However, the gas(P)-based route had the highest potential for reducing environmental burdens, and its environmental benefit was the most favourable in scenario 2050. Additionally, the economic performance of the gas(P)-based route was significantly better than that of gas(O)-based and coal-based routes.

关键词： life cycle assessment     economic performance     HFC-134a     natural gas     oil     coal    

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Liquid-based high-temperature receiver technologies for next-generation concentrating solar power: A

《能源前沿（英文）》 2023年 第17卷 第1期   页码 16-42 doi: 10.1007/s11708-023-0866-8

摘要： To reduce the levelized cost of energy for concentrating solar power (CSP), the outlet temperature of the solar receiver needs to be higher than 700 °C in the next-generation CSP. Because of extensive engineering application experience, the liquid-based receiver is an attractive receiver technology for the next-generation CSP. This review is focused on four of the most promising liquid-based receivers, including chloride salts, sodium, lead-bismuth, and tin receivers. The challenges of these receivers and corresponding solutions are comprehensively reviewed and classified. It is concluded that combining salt purification and anti-corrosion receiver materials is promising to tackle the corrosion problems of chloride salts at high temperatures. In addition, reducing energy losses of the receiver from sources and during propagation is the most effective way to improve the receiver efficiency. Moreover, resolving the sodium fire risk and material compatibility issues could promote the potential application of liquid-metal receivers. Furthermore, using multiple heat transfer fluids in one system is also a promising way for the next-generation CSP. For example, the liquid sodium is used as the heat transfer fluid while the molten chloride salt is used as the storage medium. In the end, suggestions for future studies are proposed to bridge the research gaps for > 700 °C liquid-based receivers.

关键词： next-generation concentrating solar power     liquid-based solar receiver     molten salt     liquid metals    

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Life cycle and performance based seismic design of major bridges in China

FAN Lichu

《结构与土木工程前沿（英文）》 2007年 第1卷 第3期   页码 261-266 doi: 10.1007/s11709-007-0033-z

摘要： The idea of life cycle and performance based seismic design of major bridges is introduced. Based on the key components and non-key components of a bridge and the consideration of the inspectability, replaceability, reparability, controllability and retrofitability of the bridge components, different seismic design levels and expected performance objectives are suggested for the major bridges in China. The vulnerability analysis and progressive collapse analysis, as well as risk assessment, are also proposed to be the important issues to study in order to guide the seismic design of major bridges in the future.

关键词： controllability     progressive     reparability     different     important    

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太阳能技术对我国未来减排CO2 的贡献

赵玉文

《中国工程科学》 2003年 第5卷 第4期   页码 38-40

摘要：

在“我国后续能源发展战略研究”基础上对太阳能技术在我国未来减排CO2中的作用进行了估计，结果表明，在2010年后太阳能技术对CO2

关键词： 太阳能，CO2减排    

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Photoreduction adjusted surface oxygen vacancy of BiMoO for boosting photocatalytic redox performance

《化学科学与工程前沿（英文）》 2023年 第17卷 第12期   页码 1937-1948 doi: 10.1007/s11705-023-2353-5

摘要： In this study, Bi2MoO6 with adjustable rich oxygen vacancies was prepared by a novel and simple solvothermal-photoreduction method which might be suitable for a large-scale production. The experiment results show that Bi2MoO6 with rich oxygen vacancies is an excellent photocatalyst. The photocatalytic ability of BMO-10 is 0.3 and 3.5 times higher than that of the pristine Bi2MoO6 for Rhodamine B degradation and Cr(VI) reduction, respectively. The results display that the band energy of the samples with oxygen vacancies was narrowed and the light absorption was broadened. Meanwhile, the efficiency of photogenerated electron-holes was increased and the separation and transfer speed of photogenerated carriers were improved. Therefore, this work provides a convenient and efficient method to prepare potential adjustable oxygen vacancy based photocatalysts to eliminate the pollution of dyes and Cr(VI) in water.

关键词： Bi2MoO6     oxygen vacancies     photoreduction     Cr(VI)     RhB    

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Corrosion behavior of Fe–Cr–Ni based alloys exposed to molten MgCl2–KCl–NaCl salt with over-added

《化学科学与工程前沿（英文）》 2023年 第17卷 第10期   页码 1608-1619 doi: 10.1007/s11705-023-2349-1

摘要： MgCl2–NaCl–KCl salts mixture shows great potential as a high-temperature (> 700 °C) thermal energy storage material in next-generation concentrated solar power plants. Adding Mg into molten MgCl2–NaCl–KCl salt as a corrosion inhibitor is one of the most effective and cost-effective methods to mitigate the molten salt corrosion of commercial Fe–Cr–Ni alloys. However, it is found in this work that both stainless steel 310 and Incoloy 800H samples were severely corroded after 500 h immersion test at 700 °C when the alloy samples directly contacted with the over-added Mg in the liquid form. The corrosion attack is different from the classical impurity-driven corrosion in molten chloride salts found in previous work. Microscopic analysis indicates that Ni preferentially leaches out of alloy matrix due to the tendency to form MgNi2/Mg2Ni compounds. The Ni-depletion leads to the formation of a porous corrosion layer on both alloys, with the thickness around 204 µm (stainless steel 310) and 1300 µm (Incoloy 800H), respectively. These results suggest that direct contact of liquid Mg with Ni-containing alloys should be avoided during using Mg as a corrosion inhibitor for MgCl2–NaCl–KCl or other chlorides for high temperature heat storage and transfer.

关键词： concentrated solar power (CSP)     Mg corrosion inhibitor     Mg–Ni intermetallic     salt purification     thermal energy storage (TES)    

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Thermochemical pretreatment of meat and bone meal and its effect on methane production

Guangxue WU , Zhenhu HU , Mark G. HEALY , Xinmin ZHAN ,

《环境科学与工程前沿（英文）》 2009年 第3卷 第3期   页码 300-306 doi: 10.1007/s11783-009-0031-6

摘要： Since the solubilization of meat and bone meal (MBM) is a prerequisite in many MBM disposal approaches, enhancement of the solubilization by means of thermochemical pretreatment was investigated in this study at two temperatures (55°C and 131°C) and six sodium hydroxide (NaOH) concentrations (0, 1.25, 2.5, 5, 10 and 20g/L). The MBM volatile solid (VS) reduction ratio was up to 66% and 70% at 55°C and 131°C, respectively. At the same temperature, the VS reduction ratio increased with the increase in the dosage of NaOH. The study on the methane (CH) production potential of pretreated MBM shows that the addition of NaOH at 55°C did not cause the inhibition of the succeeding CH production process. However, CH production was inhibited by the addition of NaOH at 131°C. The CH production potential was in the range of 389 to 503mL CH/g VS MBM and 464 to 555mL CH/g VS MBM at 55°C and 131°C, respectively.

关键词： thermochemical pretreatment     meat and bone meal     solid reduction     solid solubilization     methane production potential    

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标题 作者 时间 类型 操作

Thermodynamic assessment of hydrogen production via solar thermochemical cycle based on MoO

Jiahui JIN, Lei WANG, Mingkai FU, Xin LI, Yuanwei LU

期刊论文

Analysis of radiation heat transfer and temperature distributions of solar thermochemical reactor for

Bachirou GUENE LOUGOU, Yong SHUAI, Xiang CHEN, Yuan YUAN, Heping TAN, Huang XING

期刊论文

Revealing the GHG reduction potential of emerging biomass-based CO utilization with an iron cycle system

期刊论文

Piezocatalytic performance of FeO−BiMoO catalyst for dye degradation

期刊论文

中国高温气冷堆制氢发展战略研究

张平,徐景明,石磊,张作义

期刊论文

下一代太阳能光热电站中熔融氯盐技术研发进展

丁文进, Thomas Bauer

期刊论文

Review of the direct thermochemical conversion of lignocellulosic biomass for liquid fuels

Jianchun JIANG,Junming XU,Zhanqian SONG

期刊论文

SiO2 passivation layer grown by liquid phase deposition for silicon solar cell application

Yanlin CHEN,Sihua ZHONG,Miao TAN,Wenzhong SHEN

期刊论文

Life cycle assessment and economic analysis of HFC-134a production from natural gas compared with oil-basedand coal-based production

期刊论文

Liquid-based high-temperature receiver technologies for next-generation concentrating solar power: A

期刊论文

Life cycle and performance based seismic design of major bridges in China

FAN Lichu

期刊论文

太阳能技术对我国未来减排CO2 的贡献

赵玉文

期刊论文

Photoreduction adjusted surface oxygen vacancy of BiMoO for boosting photocatalytic redox performance

期刊论文

Corrosion behavior of Fe–Cr–Ni based alloys exposed to molten MgCl2–KCl–NaCl salt with over-added

期刊论文

Thermochemical pretreatment of meat and bone meal and its effect on methane production

Guangxue WU , Zhenhu HU , Mark G. HEALY , Xinmin ZHAN ,

期刊论文